Bis(O-ethyl dithiocarbonato-κ2 S,S′)bis(pyridine-3-carbonitrile-κN 1)nickel(II)
نویسندگان
چکیده
The Ni(2+) ion in the title complex, [Ni(C(3)H(5)OS(2))(2)(C(6)H(4)N(2))(2)], is in a strongly distorted octa-hedral coordination environment formed by an N(2)S(4) donor set, with the Ni(2+) ion located on a centre of inversion. In the crystal, weak C-H⋯S and C-H⋯N inter-actions are observed.
منابع مشابه
Bis(O,O′-diphenethyl dithiophosphato-κ2 S,S′)bis(4-methylpyridine-κN)nickel(II)
The title complex, [Ni(C(16)H(18)O(2)PS(2))(2)(C(6)H(7)N)(2)], exhibits a roughly octa-hedral coordination geometry. The Ni(II) atom lies on an inversion centre and is coordinated by four S atoms of O,O'-diphenethyl dithio-phosphate mol-ecules and two N atoms of 4-methyl-pyridine mol-ecules. Important geometric data include Ni-N = 2.100 (3) Å, and Ni-S = 2.5101 (10) and 2.4772 (11) Å.
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012